Crystal structure of bis[4-chloro-6-bromo-2-(cyclohexylaminmethyl)-phenolato]copper(II), Cu(C13H14BrClNO)2

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2-Bromo-4-chloro-6-(cyclo­hexyl­imino­meth­yl)phenol

The title compound, C(13)H(15)BrClNO, was prepared by the condensation of equimolar quanti-ties of 3-bromo-5-chloro-salicyl-aldehyde with cyclo-hexyl-amine in methanol. There is an intra-molecular O-H⋯N hydrogen bond in the mol-ecule. The cyclo-hexyl ring adopts a chair conformation.

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2-Bromo-4-chloro-6-(cyclo­pentyl­imino­meth­yl)phenol

All atoms of the title mol-ecule, C(12)H(13)BrClNO, except the C and H atoms of the cyclo-pentane methyl-ene groups lie on a crystallographic mirror plane. The cyclo-pentane ring adopts an envelope conformation and an intra-molecular O-H⋯N hydrogen bond is observed. In the crystal, mol-ecules are stacked along the b axis by π-π inter-actions [centroid-centroid distance = 3.6424 (11) Å].

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Crystal structure of 3-bromo­methyl-2-chloro-6-(di­bromo­meth­yl)quinoline

In the title compound, C11H7Br3ClN, the quinoline ring system is approximately planar (r.m.s. = 0.011 Å). In the crystal, mol-ecules are linked by C-H⋯Br inter-actions forming chains along [10-1]. The chains are linked by C-H⋯π and π-π inter-actions involving inversion-related pyridine rings [inter-centroid distance = 3.608 (4) Å], forming sheets parallel to (10-1). Within the sheets, there are...

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Crystal structure of 2-amino-pyridinium 6-chloro-nicotinate.

In the title salt, C5H7N(+)·C6H3ClNO(-), the 2-amino-pyri-din-ium cation inter-acts with the carboxyl-ate group of the 6-chloro-nicotinate anion through a pair of independent N-H⋯O hydrogen bonds, forming an R 2 (2)(8) ring motif. In the crystal, these dimeric units are connected further via N-H⋯O hydrogen bonds, forming chains along [001]. In addition, weak C-H⋯N and C-H⋯O hydrogen bonds, toge...

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Crystal structure of ethyl 2-chloro-6-methyl­quinoline-3-carboxyl­ate

In the title compound, C13H12ClNO2, the dihedral angle between the planes of the quinoline ring system (r.m.s. deviation = 0.029 Å) and the ester group is 54.97 (6)°. The C-O-C-Cm (m = meth-yl) torsion angle is -140.62 (16)°. In the crystal, mol-ecules inter-act via aromatic π-π stacking [shortest centroid-centroid separation = 3.6774 (9) Å] generating (010) sheets.

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ژورنال

عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures

سال: 2010

ISSN: 2197-4578,1433-7266

DOI: 10.1524/ncrs.2010.0010